How to fill small gas cylinders from a large one with a transfer pump, safely and without overfilling.

Not with these pumps. They move gas from a larger cylinder to a smaller one; the other way round needs a higher-pressure pump.
About 2 kg of gas per minute with the 12V or 220V pump.
For a business filling cylinders all day, the 1 HP commercial pump or the 1 HP belt-drive pump is made for heavy use.
LPG is moved as a liquid. Upside down, the liquid reaches the outlet, so the transfer is fast and complete.
The 220V AC pump is 7 kg packed and plugs into any 220V socket. Message us for one total price, pump and shipping together.